Wisconsin Alumni Research Foundation

Materials & Chemicals
Materials Chemicals
ELECTROCHEMICAL DEHYDROGENATION, EPOXIDATION, SUBSTITUTION, AND HALOGENATION OF HYDROCARBONS AND HYDROCARBON DERIVATIVES
WARF: P200384US02

Inventors: Marcel Schreier, Christine Lucky


The Invention
UW-Madison researchers have developed a new electrochemical method for synthesizing epoxides from hydroxy-alkanes. The method is implemented in a reactor comprising an anode and a cathode separated by an ion exchange membrane. A solution of water, halogen ions, and a hydroxy-alkane are added to the reactor, after which an electrical potential is applied. Upon application, the halogen ions react with the hydroxy-alkane at the anode to generate a halogenated hydroxy-alkane intermediate (i.e., anolyte). At the cathode, hydroxyl radicals are produced as a catholyte. The anolyte and catholyte are then contacted to generate an epoxide.
For current licensing status, please contact Michael Carey at [javascript protected email address] or 608-960-9867

WARF